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Climate change and energy

Solar panels are a pain to recycle. These companies are trying to fix that.

A new plant in France aims to extract silver from old solar panels to make recycling them worth the trouble.

August 19, 2021
recycle solar panels concept
Ms Tech | Pixel Squid

Millions of solar panels have been installed in the last two decades—and since they typically last between 25 and 30 years, many will soon be ready for retirement and probably headed to a landfill. But new efforts to recycle these panels could reduce both the amount of waste and the new material that needs to be mined.

Only about 10% of panels in the US are recycled—it isn’t mandated by federal regulations, and recycling the devices is currently much more expensive than just discarding them. But the materials in solar panels coming offline each year could be worth an estimated $2 billion by 2050. New efforts, including one approach from a French startup called ROSI, are trying to recapture these valuable materials, especially silver and silicon, to make recycling the panels more financially viable.

Expanding solar-power production is key to reducing emissions worldwide. Globally, solar panels produced 720 terawatt-hours of energy in 2019, accounting for around 3% of the world’s electricity generation. And it took about 46 million metric tons of solar panels to do it.

About 8 million metric tons of decommissioned solar panels could accumulate globally by 2030. By 2050, that number could reach 80 million. Recycling these panels could provide a new source for materials that would otherwise need to be mined (potentially under unsafe or exploitative working conditions), making solar a more sustainable piece of the clean-energy puzzle.

What’s in a solar panel?

Solar panels are laid out like a sandwich with cells in the center. About 90% of commercial solar panels use silicon as the semiconductor, which converts light into electricity. Thin strips of metal, usually silver, crisscross the surface of silicon crystals in each cell and move electricity into the panel’s copper wiring.

The solar cells are encased in a protective barrier, usually a transparent plastic called EVA. Another layer of glass goes on top, and a different kind of plastic, like PET, covers the back. The whole thing is surrounded by an aluminum frame.

This layered construction protects cells from the elements while allowing sunlight through, but it can be difficult to deconstruct when the panels have reached the end of their life.

A second life

Some companies try to refurbish and reuse panels that have lost efficiency, or at least rescue some of their components. Reuse is the simplest and cheapest way to “recycle” panels—it requires the least processing and commands the highest price.

A panel might cost around $55, while a used panel might be resold for around $22. Or the used panel’s components might be sold for a total of up to $18, according to Meng Tao, an engineering professor at Arizona State University and founder of a solar-panel recycling startup called TG Companies.

Although some resellers offer used panels for sale to residential customers, they don’t offer much price savings. Panels only make up, at most, about half the cost of a residential solar array, with the other equipment and permits accounting for the rest. Given that used panels don’t generate as much electricity, the money saved by buying them might not be worth it.

Used panels that can’t be resold are destined for either the landfill or some type of recycling. In the absence of federal mandates, Washington recently passed recycling requirements for manufacturers, and other states are now considering doing the same. The EU, meanwhile, requires manufacturers to collect and recycle used solar panels and fund research on end-of-life solutions for the technology they produce.

About 8 million metric tons of decommissioned solar panels could accumulate by 2030.

Some waste facilities can recycle solar panels using mechanical methods. Most pop off the aluminum frame and grind all the glass, silicon, and other metals into a mixture called glass cullet, which can be sold for building materials or other industrial applications.

But cullet isn’t worth much—around $3 for a panel’s worth of the mixture. And it’s not clear if there will be buyers for all the cullet that would result from recycling many more solar panels, Tao says. Being able to extract pure, valuable materials might help make recycling more profitable.

In 2018 the waste management company Veolia, based near Paris, opened what it says is the first recycling line developed specifically for recycling solar panels. Located in Rousset, France, the plant also uses a mechanical recycling process, although since it’s designed for solar panels, more components are recycled separately than at facilities using general e-waste recycling equipment. But some companies are betting that other methods, like thermal and chemical processes, will be even more efficient.

Mining old panels

ROSI Solar, a French startup founded in 2017, recently announced plans to build a new recycling plant in Grenoble, France. Yun Luo, ROSI’s CEO, says the company has developed a process to extract the silver, silicon, and other high-value materials from used panels. The plant should open before the end of 2022 with a contract from Soren, a French trade association.

Soren is also working with a French logistics company called Envie 2E Aquitaine, which will try to find other uses for decommissioned solar panels. If the panels aren’t operational, the company will remove the aluminum frame and glass before passing them along to ROSI to recycle, Luo says.

ROSI focuses on recovering silver and high-purity silicon, since these two materials make up over 60% of a panel’s cost. The company uses a proprietary chemical process on the remaining layers, focusing on removing the tiny silver threads that transmit electricity through a working solar panel.

Luo declined to go into specifics but says the company can recover nearly all the silver in a solid form, so it’s easier to separate from the other metals, like lead and tin. Luo says that the company also recovers the silicon in a pure enough form to process and reuse in new panels or EV batteries.

To be profitable, ROSI will need to recycle at least 2,000 to 3,000 tons of panels per year, Luo says. Soren expects to collect about 7,000 tons of panels in 2021, and that number will probably more than double by 2025.

However, prices for the recycled materials can be fairly volatile. When Tao published a review paper on solar-panel recycling in June 2020, he calculated that the value of raw materials that could be extracted from a used panel would be around $10. By June 2021, he says, that number had nearly doubled, to $19, because of a jump in the price of solar-grade silicon. That increase made him rethink the recycling process he’s developing for his own startup.

This price volatility means that the economics for recycling remain uncertain. And because silver is so expensive and limited, some researchers are working to reduce or even replace silver in new solar panels. While this could drive their price down further, it would also cut into the economic case for recycling, Tao says.

What remains to be seen is the environmental impact of the recycling efforts themselves. Quantifying the effects they will have on pollution and emissions can help in deciding on the best approach to the solar-waste problem, says Garvin Heath, a senior energy sustainability analyst at the National Renewable Energy Laboratory. Heath is an expert in life-cycle analysis, which tallies up the environmental impacts of a technology from its production all the way to the end of its life.

The way a technology affects the environment while it’s in use doesn’t always tell the full story. Manufacturing, transporting, and disposing of any technology generates emissions, and it’s important to take all of that into account, Heath says. Exactly how a panel is manufactured and recycled helps determine how helpful it really is in decreasing emissions.

It’s a calculation we should consider for most of the technology we use every day, Heath adds. The total amount of global e-waste could hit 120 million metric tons annually by 2050, according to a UN report.

“All technology has an end of life,” Heath says, “and you have to manage these technologies at that point.”

This story previously stated that ROSI recovers PV-grade silicon. It has been corrected to note that additional processing would be required to purify the recovered silicon to PV-grade.

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